Wetting effect on optical sum frequency generation (SFG) spectra of D-glucose, D-fructose, and sucrose

(Graph Presented) We report a sum frequency generation (SFG) spectroscopy study of D-glucose, D-fructose and sucrose in the C-H stretching vibration regime. Wetting effect on the SFG spectra was investigated. The SFG spectrum of D-glucose changed from that of α-D-glucose into those of α-D-glucose monohydrate by wetting. The SFG spectra showed evidence of a small change of β-D-fructopyranose into other anomers by wetting. SFG spectra of sucrose did not change by wetting. Assignments of the vibrational peaks in the SFG spectra of the three sugars in the dry and wet states were performed in the C-H stretching vibration region near 3000 cm-1.

Title: Wetting effect on optical sum frequency generation (SFG) spectra of D-glucose, D-fructose, and sucrose
Authors: Hoang, Chi Hieu
Li, Hongyan
Miyauchi, Yoshihiro
Mizutani, Goro
Fujita, Naoko
Nakamura, Yasunori
Keywords: Fructose;Spectroscopy;Optical sum frequency generation (SFG);Stretching vibrations;Optical Phenomena;C-H stretching regime
Issue Date: 2015
Publisher: Elsevier
Citation: Scopus
Abstract: (Graph Presented) We report a sum frequency generation (SFG) spectroscopy study of D-glucose, D-fructose and sucrose in the C-H stretching vibration regime. Wetting effect on the SFG spectra was investigated. The SFG spectrum of D-glucose changed from that of α-D-glucose into those of α-D-glucose monohydrate by wetting. The SFG spectra showed evidence of a small change of β-D-fructopyranose into other anomers by wetting. SFG spectra of sucrose did not change by wetting. Assignments of the vibrational peaks in the SFG spectra of the three sugars in the dry and wet states were performed in the C-H stretching vibration region near 3000 cm-1.
Description: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Volume 138, 5 March 2015, Pages 834-839
URI: http://www.sciencedirect.com/science/article/pii/S1386142514016059
http://repository.vnu.edu.vn/handle/VNU_123/32525
ISSN: 13861425
Appears in Collections:Bài báo của ĐHQGHN trong Scopus

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